Synthesis of Germane-stannane Copolymers using Electrochemically Generated Germyl Dianions
نویسندگان
چکیده
منابع مشابه
Tetrakis(sulfurdiimido)silane, -germane and -stannane
Z. Naturforsch. 53 b, 573-580 (1998); received March 30, 1998 Silicon, Germanium, Tin, Sulfur Diimides, Heterocycles, NMR Data Two tetrakis(sulfurdiimido)silanes [Si(NSNR)4 (R = rBu la, SiMe3 lb)], two germanes [Ge(NSNR)4 (R = rBu 2a, SiMe3 2b)] and one stannane [Sn(NSN?Bu)4Sn 3a] were prepared and characterised by 'H, l3C, i5N, 29Si and ll9Sn NMR spectroscopy in solution, and 3a was also studi...
متن کاملSolid-state structures of the covalent hydrides germane and stannane.
The low-temperature crystal structures of perdeuterogermane (m.p. 108 K) and perdeuterostannane (m.p. 123 K) are reported. The structures have been characterized from low-temperature (5 K) high-resolution neutron powder diffraction experiments following sample preparation using in situ gas-condensation techniques. GeD(4) crystallizes in an orthorhombic structure, space group P2(1)2(1)2(1), with...
متن کاملMicrofluidic actuation using electrochemically generated bubbles.
Bubble-based actuation in microfluidic applications is attractive owing to elementary microfabrication requirements. In the present study, the mechanical and chemical characteristics of electrochemically generated bubble valves were studied. By generating electrochemical bubbles as valves directly inside the channel, valves could be closed and opened in milliseconds. Whereas bubble inflation (o...
متن کاملsynthesis of amido alkylnaphthols using nano-magnetic particles and surfactants
we used dbsa and nano-magnetic for the synthesis of amido alkylnaphtols.
15 صفحه اولOrganic reactions mediated by electrochemically generated ArS+.
Low-temperature electrochemical oxidation of ArSSAr was carried out to generate a pool of "ArS(+)". Spectroscopic studies ((1)H NMR and CSI-MS) of the resulting solution revealed the accumulation of ArS(ArSSAr)(+). The resulting "ArS(+)" pool reacted with alkenes and alkynes to give diarylthio-substituted products. The "ArS(+)" pool rapidly reacted with thioacetals to give the corresponding alk...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Electrochemistry
سال: 2008
ISSN: 2186-2451,1344-3542
DOI: 10.5796/electrochemistry.76.891